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As it was I fought well over 150 engagements during a seventy hour Career mode run - and this was with the “Speed up battles” option turned on throughout - and there’s no tactical strategy game I know of that can prevent fatigue from creeping in when you’re asked to do that many encounters. I crunched the numbers and figured I’d need to do somewhere in the region of 200 maximum-difficulty contracts before I maxed out the C-Bills and Contracts scoring categories. It’s not without serious problems, though, as Harebrained have massively overcooked it by giving it a 1200 day time limit and making some of the scoring goals fantastically grindy. I personally think it should be considered the primary gameplay mode of the game from this point onwards, as I can’t see anyone ever wanting to voluntarily sit through some of the campaign missions a second time. Obviously Career mode has the long-term gameplay goal of building up to being able to field a full lance of Assault-class ‘mechs with additional spares, but you’re also given a Career mode score and ranking that’s built up through a series of Pirates!-esque scoring categories, like collecting one of every Battlemech or maxing out your friendly/enemy reputation with each noble house.Ĭareer mode is a fine addition to Battletech. Contract difficulty is now fixed per-planet and no longer scales up with your MRBC rating (a proxy for contracts completed), so you can jet off to a more difficult planet to try and take on some strong opposition - and possibly salvage their ‘mechs, resulting in a power boost for your company - and then when you inevitably get shredded you can withdraw to a less difficult world while you wait for your strongest ‘mechs and mechwarriors to get out of the hospital. Career mode dumps the scripted campaign missions, the overpowered campaign mission rewards and the cliched campaign story in favour of a completely freeform experience where you start out with the unupgraded Argo and a few lighter ‘mechs and build your mercenary company up from there by doing the randomly-generated contract missions. 1.3 reworks the Mechwarrior skill trees to try and make the optimal skill build a little less of a no-brainer (which mostly succeeds) and adds Career mode, otherwise known as “what I actually wanted out of Battletech all along”. It is astonishingly anemic.įlashpoint has been released at the same time as the 1.3 patch for Battletech, and this is something that’s worth delving a little deeper into because when you consider that package as a whole it’s not actually too bad. Hell, if I didn’t like Harebrained and Battletech so much that I don’t particularly have a problem with throwing more money at them in general to support the studio, I’d be feeling pretty damn cheated by Flashpoint. Certainly I can’t think of one sitting in the £15 price bracket that adds so little. Given that track record I should like Flashpoint, the first DLC expansion for Battletech.Īlas, I instead find myself struggling to think of a non-cosmetic DLC that, when thrown into its base game, makes such a weak splash as Flashpoint does. In fact, I like Battletech so much I gave it the number two slot on my list of the top five games of 2018. Come on, Harebrained, you’re better than this. The weapons below are all support weapons and optional. It is recommended to use the Hyperion variant as it provides the most mana out of all the variants. When a variant of the Necron's Blade is clean with no scrolls, it is not an amazing weapon, but once the player applies all 3 Necron Scrolls, this sword becomes INSANELY overpowered, able to demolish any enemy in one right click. This can be paired with the Yeti Sword as the player can swap between both of them without being slowed down by the cooldown. It is recommended to put Ultimate Wise V. After it's dungeonized it is able to do over 5M ❁ Damage to mobs in Dungeons, but requires Catacombs 25. While it is one of the most expensive items in the game, the Midas Staff the second best weapon for late game and end game Mages. It is quite useful in Dungeons, but it is recommended to dungeonize it, which makes it require Catacombs 22. The Yeti Sword ability can deal massive AoE damage and can kill any Tier 4 Slayer boss except Voidglooms within seconds. With it's lower mana cost, higher damage and a slow effect, it becomes better than the Spirit Sceptre with the only downside being it has a smaller area of effect. It is mandatory to get the Ultimate Wise V.Ī direct upgrade of the Frozen Scythe, it shoots the same ice projectiles with the addition of an explosion when it lands. However, it does have a high ✎ Mana cost, so ✎ Intelligence should be maximized to use it continuously. It's a powerful weapon that shoots player-controlled bats without a cooldown, that create a 6-block radius explosion, making it one of the best weapons to clear out rooms. It is recommended to get at least Ultimate Wise III on this weapon.Ī Spirit Sceptre is an essential mage tool. It shoots out ice bolts that are slow and pierce through targets. Its main utility is using it when low on ✎ Mana, due to its low ✎ Mana cost. It is recommended to get at least Ultimate Wise III on this weapon.Ī Frozen Scythe is recommended for all mid-game users. It is also used by end-game players to get the crystals in phase one of the Necron bossfight. It is essential for any early to mid-game Mage. It should cost no more than 3,500,000 coins on BIN auctions, and has a great firing rate with AOE ❁ Damage (area of effect). The requirement is bugged however, but this might be patched soon.Ī Bonzo's Staff should ideally be the player's next weapon. Even in late-game, this weapon remains viable due to its miniscule Mana cost (10 mana). Although it has no dungeon bonuses, it still can dish out ~350,000 damage to mobs, provided you have around 3,500 Intelligence in the Catacombs. The Dreadlord Sword also can be useful for mid-game mages due to the very low mana cost of about 5k-10k.Īn Aurora Staff is quite a good weapon. Early game mages do have the option to use their strongest weapon and go directly to the Bonzo Staff. The requirement being Catacombs 5 makes this weapon even greater for early-game Mages. Taking into consideration these items' usually high requirements and their high prices, it is not recommended to play the Mage class in the early-game.Ī Dreadlord Sword is a decent budget Mage that shoots Wither Skulls, which have a large AOE. These often have requirements such as a high Catacombs level or Combat. These weapons are required or heavily recommended when playing as a Mage. For Left Click Mage, refer to the Left Click Mage guide. If you want to run master mode as mage, it is heavily recommended to run Left Click Mage with a Giant's Sword, although you will clear slower than even an Archer. And even with a high Catacombs level, many mobs are still too tanky to be defeated by a single magic weapon ability. However, in master mode, right click mage becomes obsolete due to its abysmal DPS not being even enough for even clearing. Right click mage excels in regular dungeons due the regular mobs having low enough EHP to be one shot. There are generally two playstyles for mage: Left Click Mage (mage beam) and Right Click Mage (ability spamming). There was no “Smells Like Teen Spirit,” no “In Bloom,” instead a collection of some of Cobain’s personally influential songs, like The Vaselines’ “Jesus Don’t Want Me For a Sunbeam,” “Where Did You Sleep Last Night?” by Leadbelly and David Bowie’s “The Man Who Sold The World,” the Meat Puppets’ “Plateau, deeper Nirvana tracks like “Something In the Way” and more. Originally released 25 years ago today, 'MTV Unplugged In New York' is now available digitally & as a 2LP set, including five rehearsal performances previously only available on DVD. The band’s Unplugged performance was notable for the band’s steadfast decision to play anything but many of their hits. It aired in December on MTV and was eventually released as a live album in December 1994 - a posthumous tribute to Cobain. Nirvana’s MTV Unplugged in New York was filmed in the fall of 1993, just months before Cobain was found dead. The presences of both singers were key factors in Nirvana and Alice in Chains’ rise in prominence in the 1990s, but it was each band’s MTV Unplugged performance that showed the true power of Kurt Cobain and Layne Staley as artists - tortured artists, but artists nonetheless.Ĭlick here to pick up Nirvana MTV Unplugged in New York on CD from our Rock Cellar StoreĬlick here to shop Nirvana from our Rock Cellar Store Eight years later, on April 5, 2002, Alice in Chains singer Layne Staley passed away after an overdose on cocaine and heroin - also dying in Seattle.īoth Cobain and Staley were known for pained lyrics expressing the deepest and most intense of emotions, stemming from their respective tumultuous life experiences and addictions. On April 5, 1994, Nirvana front man Kurt Cobain died by suicide in Seattle. "Killer Is Me" (Cut from MTV Broadcast, included on the re-release.Today’s date, April 5, is notorious in the world of rock and roll, as it’s the date commemorating the passing of two of the most iconic and celebrated singers of all time, Kurt Cobain and Layne Staley. "Frogs" (Cut from MTV Broadcast, included on the re-release.) "Angry Chair" (Cut from MTV Broadcast, included on the re-release.) Jerry Cantrell, Mike Inez, Sean Kinney, Layne Staley Inez and drummer Sean Kinney did pay tribute to Metallica, however, playing the intro to their hit song "Enter Sandman" just before "Sludge Factory" and the Intro to "Battery" before "Angry Chair" (this can be heard on the CD and the DVD). Mike Inez's bass had the phrase "Friends Don't Let Friends Get Friends Haircuts." written on it, directed at the members of Metallica who were in the audience and had recently cut their hair short. The performance featured some of the band's highest charting singles, including "Down in a Hole", "Heaven Beside You", and "Would?", and introduced a new song, "The Killer Is Me". The show marked Alice in Chains' first appearance as a five-piece band, adding second guitarist Scott Olson. It is often hailed as one of the most memorable editions of MTV Unplugged, with a reputation comparable to the famous editions featuring Nirvana, Eric Clapton, and Bob Dylan. The performance was one of the band's final appearances with vocalist Layne Staley. The album was re-released as a CD/DVD package on September 18, 2007. The songs "Angry Chair", "Frogs", and "The Killer Is Me" were cut from the original MTV broadcast but are included on both the CD and home video releases. The album has received platinum certification by the RIAA and the home video release has received gold certification by the RIAA. A full length DVD of the concert was also later released in 1999. A live album of the performance was released in July 1996, which debuted at number three on the Billboard 200, and was accompanied by a home video release. The show first aired on MTV on May 28, 1996. Alice in Chains resurfaced on Apto perform their first concert in two and a half years for MTV Unplugged, a program featuring all-acoustic set lists. Outside of the internet, the code plays a big role in the Disney flick Wreck It Ralph. Typing in the code on someone’s profile page causes posts on the page to go a little strange… 9. Some people have a fun spin on the sequence coded into their personal websites. Typing in the Konami Code gives you a list of… you guessed it: Konami Codes. CSSlineĬSSline is a showcase gallery of excellent CSS sites from all over the world. Jokey video game site DuelingAnalogs has hidden artwork depicting Jesus’ disciples acting out the Konami code. Not much of a secret, as it lists the Konami Code right there on the page, but heading to this site will unlock a “hidden” 1976 interview with Stark Trek legend William Shatner. SiriĪpple’s virtual assistant Siri knows the Konami Code – reciting it to her will trigger one of three responses: “Cheater!”, “Nerd.” or “I’m getting dizzy…” 4. The code to say is: “Alexa, Up, Up, Down, Down, Left, Right, Left, Right, B, A, Start.” TikTok/siri.official 3. This IT video learning site pops up a load of fun cartoon characters (watch out for Darth Vader!) Typing in the code here will give you a funky colourful background. Here are some examples of places you can access Konami Code features today… 1. The code appeared in dozens of games, and has since been repurposed by newer titles, websites and apps as an Easter egg or tribute. In Contra, the code would give the player 30 lives. The code first appeared in NES shooter Gradius, but was popularised in the US with Contra. Players would tap in the code using their controller to unlock special cheats or settings. It’s probably the most famous cheat code, famed for its use in many Konami video games. Users say Siri has been replying with “nerd” upon hearing the Konami Code. You can also try the code with Siri on your iPhone or Apple HomePod. They included “Wrong code, try again” and “Woo-hoo, power up galore”. Saying the code aloud causes Amazon’s smart speaker to “activate Super Mode” TikTok/siri.official TikTok users tried the code themselves, and reported several different phrases being returned. She has a number of canned responses for when the Konami Code is said aloud. The code to say is: “Alexa, Up, Up, Down, Down, Left, Right, Left, Right, B, A, Start”, as revealed on TikTok.īear in mind that Alexa might not always say that Super Mode has been activated. The ‘Super Mode’ doesn’t actually do anything, but instead is a whimsical tribute to the iconic video game cheat. It’s a legendary cheat code, which has been introduced to Alexa and Siri as an Easter egg. The phrase in question is the Konami Code, a string of button descriptions from classic gaming joypads. Saying the code aloud causes Amazon’s smart speaker to “activate Super Mode” – and will spark a Siri response too. Why WhatsApp is better on iPhone than AndroidĪ secret Alexa code revealed on TikTok has been viewed by millions of users. What time is the Call of Duty Warzone Pacific map out? Police warn 1.5billion WhatsApp users to delete this dangerous new text Video: Dolby Vision, HDR 10, HDR10+, HLG, H.265, H.264 and VP9.Īudio: AAC-LC, AC3, eAC3 (Dolby Digital Plus), FLAC, MP3, PCM/Wave, Vorbis and Dolby Atmos (EC3_JOC).Huge Google warning over 12 popular Android apps caught stealing bank details All services may not be available in 4K/HDR. To watch movies and TV shows in 4K Ultra HD, you need a compatible Ultra HD TV. Dolby Atmos is currently supported only on selected Prime Video titles. Note: Support varies by country, certain functions may not be available on some IR-enabled devices.įree cloud storage for digital content purchased from Amazon.ĭolby Atmos, 7.1 surround sound, 2-channel stereo, and HDMI audio pass through up to 5.1. The included Alexa Voice Remote can control Fire TV Stick 4K and certain functions (such as power and volume) on a wide range of compatible IR-enabled devices, including TVs, soundbars and A/V receivers. IR Device Control with included Alexa Voice Remote Yes, with the Alexa Voice Remote (included) or free Fire TV App (available for download on Fire OS, Android and iOS). Supports 802.11a/b/g/n/ac Wi-Fi networks.
However, IMSLP is well organized with a great selection of high-quality documents. One of my favorite parts about this website is how organized everything is.Ī lot of free music websites are hard to operate because there’s so much random music around the site, with no real direction to the site. This site has a giant collection of music with a large selection of contributing artists adding to the site daily. IMSLP stands for the International Music Score Library Project, which operates under Canadian copyright laws. Today, we’re delivering to you the best sites to get guitar music from for free! IMSLP The one thing that all of these sites have in common is that they all allow you to download music for free, which is great! After spending so much money on an instrument, you’re going to want to find some music to play, without having to spend any money. Some of these sites only offer music for guitars, while others offer music for instruments of all sorts. Some of the sites that are listed in this article are for specific genres or instruments only we have some sites that only offer operatic pieces or vintage pieces of music, but there is something here for everyone on this site. I know that I personally would prefer to spend more time playing guitar than to spend endless hours looking across the Internet to find new songs to learn on guitar. If you’ve spent some time looking for sheet music, you’ve also probably discovered that finding sheet music or free guitar tabs is extremely difficult to find. If you’re serious about learning how to play guitar, you’ve probably spent some time looking around the internet for some free sheet music to download.
It is always up-to-date with the latest news from across the region. We also have a free app which you can download. You can also get all the latest updates by following us on social media here Facebook and Twitter. If you decide later that you no longer wish to receive the emails, simply follow the unsubscribe link in one of the newsletters - but we don't think you'll want to. Simply type your email address into the box at the top of this article and hit sign up.Īnd that's it, you're all set. In our daily Aston Villa bulletin, we'll be bringing you the latest breaking news, transfer features and comment pieces, as well as the key talking points for fans. If you scroll down, the answers are at the bottom.ġ: Which club was top of League Two when play stopped in March?Ģ: The lowest Premier League attendance was 10,020 at Bournemouth - but who were the opposition?ģ: Who are the top scoring team in the Premier League?Ĥ: Which four teams had qualified for the Champions League quarter-finals?ĥ: Which club was expelled from League One in August 2019?ħ: Against which two teams did Liverpool drop points in the Premier League?Ĩ: Who did Aston Villa beat in the EFL Cup semi-final?ĩ: Who were the only League One side to reach the FA Cup last 16?ġ0: Which club is currently bottom of the Championship? Sign up to our Birmingham City newsletter here STADIUMSġ1: Which team plays home matches at Roots Hall?ġ2: What’s the highest ground above sea level in England’s top four divisions?ġ3: Which eight grounds were used at Euro 96?ġ4: Who are the most northerly, southerly, westerly and easterly clubs in England’s top four divisions?ġ5: Where do Gillingham play their home games?ġ6: Which Premier League club’s ground hosted its first game in 2011?ġ7: In which city would you find the 49,000-capacity La Bombonera stadium?ġ8: Who played their first home league game at Anfield in September 1888?ġ9: Name the top five clubs in England based on all-time average league attendanceĢ0: Which team plays home matches at Brunton Park? PREMIER LEAGUEĢ1: Who was top scorer in the first Premier League season (1992/93)?Ģ2: Which player has made the most Premier League appearances?Ģ3: Four players have made more than 100 Premier League assists - who are they?Ģ4: Who has kept the most Premier League clean sheets?Ģ5: Who is the highest all-time Premier League top scorer never to have won the title?Ģ6: Which six clubs have been promoted to the Premier League on four occasions?Ģ7: The highest scoring Premier League match is Portsmouth’s 7-4 win over which club in 2007?Ģ8: Who is the most used sub in Premier League history?Ģ9: Which three players have picked up the most Premier League red cards (eight)?ģ0: Who drew 5-5 with Manchester United in May 2013? We have split the quiz into 10 different sections, covering the 2019/20 season, the Premier League, stadiums, nicknames, international football, awards, captains, transfers, football in fiction and a category for anything else at the end. So why not try your luck with this, football-themed one. The absence of football is hardly zooming by, even if everything else is happening on Zoom.Įspecially quizzes, online trivia battles have become de rigeur during the lockdown. They have the thermodynamic data of Group I and Group II halides in Table 1. This definition causes the value for the lattice energy to always be positive, since this will always be an endothermic reaction. In one definition, the lattice energy is the energy required to break apart an ionic solid and convert its component atoms into gaseous ions. urgently c) Explain why the lattice energy of Magnesium Fluoride is more exothermic that that of calcium chloride. Faraday Soc., 1958,54, 34-39, is relevant the OP's question with actual experimental data. Lattice Energy is a type of potential energy that may be defined in two ways. A paper titled The solubilities of some inorganic halides, Trans. So may even ask, which magnesium chloride is being discussed?Īs a result, many chemists rely on macroscopic measurements such as thermodynamic properties but such properties are quiet about microscopic details and "whies". Take anhydrous $\ce$, and add it to water, the reaction is not exothermic in water, and water's pH does not change. Tools such as ChemDraw and SciFinder can provide estimates, but there is a significant margin of error in those solubility numbers and the results may be incorrect. Lattice Energy The energy associated with forming an ionic crystal from atoms Why does magnesium chloride (MgCl 2) have a larger lattice energy than calcium chloride (CaCl 2) Magnesium is in period 3 Calcium is in period 4 Cl ions get closer to the center of positive charge (core) in MgCl 2 than in CaCl 2 Mg2 cations have smaller radius. The size of the lattice energy is connected to many other physical. It is a measure of the cohesive forces that bind ionic solids. The same goes for melting and boiling points. In chemistry, the lattice energy is the energy change upon formation of one mole of a crystalline ionic compound from its constituent ions, which are assumed to initially be in the gaseous state. While it may be tempting to come up with explanations that allow us to pass exams or understand concepts on a surface level, the truth is that our current understanding of chemistry is not advanced enough to accurately predict the solubility of compounds in water or other solvents. Although it is very tempting to rationalize every laboratory observation, there are no definite answers to questions about why certain chemical phenomena occur. So factoring 254.66/2 into my equation below i ended up with a lattice energy of -863.33.There are no answers to such why questions, in case anyone is looking for an "answer". I keep finding all sorts of different enthalpy of vaporizations for bromine.free energy of solution of, 19 : 11103 CaCl2 - AgCl, phase diagrams. Use the data given to calculate an overall energy change (in kilojoules per mole) for the formation of from its elements.Įa for F = -328 E11 forCs = 375.7 E12 for Cs = 2422 Heat of sublimation for Cs = 713 CALCIUM COMPLEXES 16 : 23703 binding energy of gaseous, 16 : 28964 chloride. The estimated lattice energy for is CsF2 2347kj/mol.For calcium the first ionization energy is 589.5kJ/mol and the second ionization energy is 1146kJ/mol. Calculate the lattice energy in kJ/mol for CaCl2 from the following information: Energy needed to vaporize one mole of Ca(s) is 192kJ.the difference between the enthalpy of the the difference between the activation energy and reaction enthalpy b. A reaction is always non-spontaneous whenĪ.Assume that the energy input in this case is chemical potential energy and the useful The legacy Materials Project website remains available. Consider this energy transformation diagram. Welcome to the new Materials Project website Read our release announcement here. We know that the law of conservation of energy states that energy can not be created or destroyed.The enthalpy of formation of caesium chloride is -44.28kjmol-1 and enthalpy of sublimation of caesium is 77.66kjmol-1.With other data from other sources calculate the lattice energy of CsCl(s)?.What similarities do nuclear energy and chemical energy share? Choose all that apply.Ī. Ionization energy of Na(g): 495 kJ/mol Electron affinity of O2 for 2e: 603 kJ/mol Energy to vaporize Na(s): 109 kJ/mol O2(g) bond energy: 499 kJ/mol Energy change for the reaction calculate the lattice energy of sodium oxide (Na2O) from the following data:. Calculate the lattice energy of potassium oxide from the following data:Įnthalpy of sublimation of potassium: 89.24 kJ/mol Bond energy of oxygen: 498 kJ/mol First ionization energy of potassium: 419 kJ/mol 1st electron affinity of oxygen: -141 kJ/mol. If it is something too flashy or dull, then a fish will not recognize the prey and as a result, ignore the lure. At the same time, fish like squid and salmon feed on this type of prey, and thus, glow lures would help you hook on either one of these species.īut, that does not mean you can just hook any glowing lure and expect a bounty catch! Your glowing lure must look natural and subtle, while also imitating the characters of a prey. It is a well-known fact that bioluminescent preys are more common in saltwater areas. It’s also a tad more expensive, but it’s worth every penny.Conclusion Why Are Glow in the Dark Lures Effective? This fish is a bit more difficult to keep because it requires more attention and care. However, if you’re looking for something a little more challenging, you may want to look at the Zebra Danio. Zebra Danios are great for beginners because they’re easy to care for and they don’t require a lot of attention. They will happily eat any food you throw at them. These fish are a great addition to the community tank. The zebra danios were the source of the GloFish danios. However, fluorescent lights do emit some harmful light, so they are not recommended for use in fish tanks with fish that are sensitive to the harmful effects of UV radiation. They are also less expensive than other types of lights. If you want to keep blue lights on all the time, it is best to use a fluorescent light.įluorescent lights are more energy efficient than incandescent lights, and they do not emit any harmful UV rays. Leaving a light on at night will cause sleep deprivation for fish. If you don’t have nocturnal fish, they rely on light cycles to sleep. No, you should not keep a blue light or any other colored light on in your fish tank through the night. Can I leave blue light on in fish tank at night? GloFish can be found in freshwater, saltwater, brackish, and marine environments. A single clutch can hold hundreds of eggs. Female glofish have the ability to lay eggs. Can GloFish have babies?Ī female fish releases her pheromones to a male fish. However, if you are lucky enough to be in an area where there is a lot of natural light, you may be able to see some of the luminescent glow coming from a fish or other animal. In fact, most people can’t even see the glow from their own eyes, let alone see it from an animal’s eyes. This glow can also be detected by the human eye, but it is not as bright as that of a firefly. When the body is exposed to high levels of this chemical, it produces a glow that is visible to the naked eye. Biolumsence is caused by a chemical called luciferin, which is found in the blood of many animals. Humans can see bioluminescence in a wide variety of animals, including fireflies. Unlike most aquarium fish, the characteristic that makes them glow is called bioluminescence. However, if one of your parents has a copy of the gene and the other does not, then the offspring will be a mix of both parents’ genes. This means that if you have two copies of this gene, you will have a male and a female. The gene for the fluorescent gene is located on the X chromosome, which is the same chromosome as the Y chromosome. The naturally occurring genes that make up the fluorescent protein genes are found inbacteria andalgae. The fluorescent color in glofish can be seen when looking at the fish, as it is created by an inherited fluorescent protein gene that has been passed from generation to generation. Gloves are also a great way to keep your hands clean and free of dirt and grime, which can be a problem for many fish keepers.Ī good pair of gloves can cost anywhere from $20 to $100, depending on the quality of the gloves and the type of fish you are keeping. They are essential for keeping the fish warm and comfortable, and they can also be used to protect the eyes from the sun’s harmful UV rays. Gloves are a must-have accessory for any glo fish keeper. Fish color and variety have always been a selling point for most aquarists, so it is no surprise that they are among the most sought-after fish in the hobby. There are brilliant, bright, iridescent colors in the fish. If you want to appreciate their fluorescent glow, you need a good backlight. No, Glofish do not glow without a backlight. Can I leave blue light on in fish tank at night?. |